Yep, the ecu, the alternator, the clutch, timing belt etc can all be used from the 2.5.
I think the sensors would have to be swapped over as the plugs on the z32SE are a different shape.
You will also need the inlet and fuel rail etc from your original engine.
You can keep the sump that's on the new lump though.
I'm going to get a new thermostat as it has to be the one from the 3.2 as it's a different part on the 2.5, new heat exchanger, new water pump, thinking about a clutch as although the original will fit the recommendation is to fit the one from the 2.6 as it's slightly bigger, you just need to get a new thrust bearing as the 2.6 is from a vectra which has a hydraulic slave cylinder.
I've already got a lightened flywheel and I'm going to get new induction, top and bottom and ancillary silicone hoses just cause my originals are looking a bit tired.
If you've got the funds it may be worth getting a new alternator as it's a much easier job while the engine's out!
If you're uprating manifolds and down pipes this is the time to do those as well but definately get new manifold gaskets.
I think the 3.2 has plastic cam covers but the Veccy B cam covers will fit.